Physical Chemistry

Physical Chemistry by Prof. Robert Field via MIT

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Created by Massachusetts Institute of Technology Staff Last updated Mon, 28-Feb-2022 English


Physical Chemistry free videos and free material uploaded by Massachusetts Institute of Technology Staff .

Syllabus / What will i learn?

Historical Background, Photoelectric Effect

Wave Nature of the Electron and the Internal Structure of an Atom

Two-Slit Experiment, Quantum Weirdness

Classical Wave Equation and Separation of Variables

Quantum Mechanics: Free Particle and Particle in 1D box

3-D Box and QM Separation of Variables

Classical Mechanical Harmonic Oscillator

Quantum Mechanical Harmonic Oscillator

The Harmonic Oscillator: Creation and Annihilation Operators

The Time-Dependent Schrödinger Equation

Wavepacket Dynamics for Harmonic Oscillator and PIB

Catch Up and Review, Postulates

From Hij Integrals to H Matrices I

From Hij Integrals to H Matrices II

Non-Degenerate Perturbation Theory I

Non-Degenerate Perturbation Theory II: HO using a,a

Rigid Rotor I. Orbital Angular Momentum

Rigid Rotor II. Derivation by Commutation Rules

Spectroscopy: Probing Molecules with Light

Hydrogen Atom I

Hydrogen Atom II. Rydberg States

Helium Atom

Many-Electron Atoms

Molecular Orbital Theory I. Variational Principle and Matrix Mechanics

Molecular Orbital Theory II. H2+, A2, AB Diatomics

Qualitative MO Theory: Hückel

Non-Degenerate Perturbation Theory III

Modern Electronic Structure Theory: Basis Sets

Modern Electronic Structure Theory: Electronic Correlation

Time-Dependent Perturbation Theory I. H is Time-Independent, Zewail Wavepacket

Time-Dependent Perturbation Theory II. 

H is Time-Dependent: Two-Level Problem

Intermolecular Interactions by Non-Degenerate Perturbation Theory

Electronic Spectroscopy: Franck-Condon

Electronic Spectroscopy and Photochemistry

δ-Functions, Eigenfunctions of X, Discrete Variable Representation

Time Dependence of Two-Level Systems: Density Matrix, Rotating Wave

 



Curriculum for this course
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Description

This course is an introduction to quantum mechanics for use by chemists. Topics include particles and waves, wave mechanics, semi-classical quantum mechanics, matrix mechanics, perturbation theory, molecular orbital theory, molecular structure, molecular spectroscopy, and photochemistry. Emphasis is on creating and building confidence in the use of intuitive pictures.

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